## Isotopes of aluminium

### Naturally occurring isotopes

This table shows information about naturally occuring isotopes, their atomic masses, their natural abundances, their nuclear spins, and their magnetic moments. Further data for radioisotopes (radioactive isotopes) of aluminium are listed (including any which occur naturally) below.
Isotope Atomic mass (ma/u) Natural abundance (atom %) Nuclear spin (I) Magnetic moment (μ/μN)
27Al 26.9815386 (8) 100 5/2 3.641504

In the above picture, the most intense ion is set to 100% since this corresponds best to the output from a mass spectrometer. This is not to be confused with the relative percentage isotope abundances which total 100% for all the naturally occurring isotopes.

Further data for naturally occuring isotopes of aluminium are listed above. This table gives information about some radiosotopes of aluminium, their masses, their half-lives, their modes of decay, their nuclear spins, and their nuclear magnetic moments.
Isotope Mass Half-life Mode of decay Nuclear spin Nuclear magnetic moment
24Al 23.999941 2.07 s EC + α to 20Ne; EC to 24Mg 4 3.646
25Al 24.990429 7.17 s EC to 25Mg 5/2
26Al 25.986892 710000 y EC to 26Mg 5
28Al 27.981910 2.25 m β- to 28Si 3 3.24
29Al 28.980446 6.5 m β- to 29Si 5/2
30Al 29.98296 3.68 s β- to 30Si 3

### Sheffield ChemPuter isotope pattern calculator

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### References

1. Naturally occurring isotope abundances: Commission on Atomic Weights and Isotopic Abundances report for the International Union of Pure and Applied Chemistry in Isotopic Compositions of the Elements 1989, Pure and Applied Chemistry, 1998, 70, 217. [Copyright 1998 IUPAC]
2. For further information about radioisotopes see Jonghwa Chang's (Korea Atomic Energy Research Institute) Table of the Nuclides
3. Masses, nuclear spins, and magnetic moments: I. Mills, T. Cvitas, K. Homann, N. Kallay, and K. Kuchitsu in Quantities, Units and Symbols in Physical Chemistry, Blackwell Scientific Publications, Oxford, UK, 1988. [Copyright 1988 IUPAC]

## NMR Properties of aluminium

Common reference compound: Al(NO3)3/D2O, 1.1 mol kg-1.

Isotope 1 Isotope 2 Isotope 27Al Natural abundance /% 100 Spin (I) 5/2 Frequency relative to 1H = 100 (MHz) 26.056859 Receptivity, DP, relative to 1H = 1.00 0.207 Receptivity, DC, relative to 13C = 1.00 1220 Magnetogyric ratio, γ (107 rad T-1 s-1) 6.9762715 Magnetic moment, μ (μN) 4.3086865 Nuclear quadrupole moment, Q/millibarn 146.6(10) Line width factor, 1056l (m4) 69

### References

1. R.K. Harris in Encyclopedia of Nuclear Magnetic Resonance, D.M. Granty and R.K. Harris, (eds.), vol. 5, John Wiley & Sons, Chichester, UK, 1996. I am grateful to Professor Robin Harris (University of Durham, UK) who provided much of the NMR data, which are copyright 1996 IUPAC, adapted from his contribution contained within this reference.
2. J. Mason in Multinuclear NMR, Plenum Press, New York, USA, 1987. Where given, data for certain radioactive nuclei are from this reference.
3. P. Pyykkö, Mol. Phys., 2008, 106, 1965-1974.
4. P. Pyykkö, Mol. Phys., 2001, 99, 1617-1629.
5. P. Pyykkö, Z. Naturforsch., 1992, 47a, 189. I am grateful to Professor Pekka Pyykkö (University of Helsinki, Finland) who provided the nuclear quadrupole moment data in this and the following two references.
6. D.R. Lide, (ed.), CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Florida, USA, 79th edition, 1998.
7. P. Pyykkö, personal communication, 1998, 204, 2008, 2010.
8. The isotopic abundances are extracted from the naturally occurring isotopes section within WebElements.

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