Chlorine compounds

This section lists some binary compounds with halogens (known as halides), oxygen (known as oxides), hydrogen (known as hydrides), and some other compounds of chlorine. For each compound, a formal oxidation number for chlorine is given, but the usefulness of this number is limited for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only. The term hydride is used in a generic sense to indicate compounds of the type M_xH_y and not necessarily to indicate that any compounds listed behave chemically as hydrides. In compounds of chlorine (where known), the most common oxidation numbers of chlorine are: 7, 5, 3, 1, and -1.

Hydrides

The term hydride is used to indicate compounds of the type M_xH_y and not necessarily to indicate that any compounds listed behave as hydrides chemically.

• none listed

Fluorides

• Chlorine fluoride: ClF
• Chlorine trifluoride: ClF₃
• Chlorine pentafluoride: ClF₅

Chlorides

• none listed

Bromides

• none listed

Iodides

• none listed

Oxides

• Chlorine dioxide: ClO₂
• Dichlorine oxide: Cl₂O
• Dichlorine hexoxide: Cl₂O₆
• Dichlorine heptoxide: Cl₂O₇

Sulfides

• none listed

Selenides

• none listed

Tellurides

• none listed

Nitrides

• none listed

Carbonyls

• none listed

Complexes

• none listed

Standard Reduction Potentials

References

The standard reduction potentials given here for aqueous solutions are adapted from the IUPAC publication reference 1 with additional data and an occasional correction incorporated from many other sources, in particular, references 2-7.

1. A.J. Bard, R. Parsons, and J. Jordan, Standard Potentials in Aqueous Solutions, IUPAC (Marcel Dekker), New York, USA, 1985.
2. N.N. Greenwood and A. Earnshaw, Chemistry of the Elements, 2nd edition, Butterworth-Heinemann, Oxford, UK, 1997.
3. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5th edition, John Wiley & Sons, New York, USA, 1988.
4. B. Douglas, D.H. McDaniel, and J.J. Alexander, Concepts and models of Inorganic Chemistry, 2nd edition, John Wiley & Sons, New York, USA, 1983.
5. D.F. Shriver, P.W. Atkins, and C.H. Langford, Inorganic Chemstry, 3rd edition, Oxford University Press, Oxford, UK, 1999.
6. J.E. Huheey, E.A. Keiter, and R.L. Keiter in Inorganic Chemistry : Principles of Structure and Reactivity, 4th edition, HarperCollins, New York, USA, 1993.
7. G.T. Seaborg and W.D. Loveland in The elements beyond uranium, John Wiley & Sons, New York, USA, 1990.

WebElements Shop

WebElements now has an online shop at which you can buy periodic table posters, mugs, T-shirts, games, molecular models, and more.

Chlorine	Chlore
Chlor	Chloor
Cloro	Cloro
Klor	Cloro