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Lithium compounds: lithium hydroxide monohydrate
The lithium in lithium hydroxide monohydrate formally is in the oxidation state 1.
Lithium hydroxide monohydrate
- Formula as often written: LiOH.H2O
- Hill system formula: H3Li1O2
- CAS registry number: [1310-66-3]
- Formula weight: 41.964
- Class: complex
Synonyms
- lithium hydroxide monohydrate
- lithium(I) hydroxide monohydrate
- lithium hydroxide 1-water
Physical properties
- Colour: white
- Appearance: crystalline solid
- Melting point:
- Boiling point:
- Density: 1510 kg m-3
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Element analysis
Element percentages for the elements in lithium hydroxide monohydrate
| Element |
% |
| H |
7.21 |
| Li |
16.54 |
| O |
76.25 |
Synthesis
One way to prepare lithium(I) hydroxide is the reaction between lithium (I) sulphate and barium hydroxide, Ba(OH)2.
Li2SO4(aq) + Ba(OH)2(aq) → 2LiOH(aq) + BaSO4(s)
Isotope pattern
What follows is the calculated isotope pattern for the LiOH.H2O unit with the most intense ion set to 100%.
Formula: Li1O2H3
mass %
41 8.1 ____ 42 100.0 __________________________________________________ 43 0.1 44 0.4
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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