Chemical reactions of the elementsReaction of palladium with airHeating palladium metal with oxygen results in formation of palladium(II) oxide, PdO. 2Pd(s) + O2(g) → PdO(s) [black] Reaction of palladium with waterReaction of palladium with the halogensCareful control of the reaction between palladium metal and fluorine gas, F2, results in either the palladium trifluoride. This compound is not palladium(III) fluoride but the mixed valence Pd(II,IV) salt [Pd]2+[PdF6]2-. 2Pd(s) + 3F2(g) → [Pd][PdF6](s) The dichloride, palladium(II) chloride, PdCl2, is also formed in the controlled reaction of palladium metal and chlorine, Cl2. Depending upon the reaction conditions, one of two different forms of PdCl2 is formed. In a related reaction, the dibromide, palladium(II) bromide, PdBr2, is formed in the reaction of palladium metal and bromine, Br2. Pd(s) + Cl2(g) → PdCl2(s) [red, second form colour ...?] Pd(s) + CBr2(g) → PdBr2(s) [red-black] Reaction of palladium with acidsReaction of palladium with basesWebElements ShopWebElements now has a WebElements shop at which you can buy periodic table posters, mugs, T-shirts, games, molecular models, and more. |
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