Terbium - 65Tb: the essentials
Terbium atoms have 65 electrons and the shell structure is 126.96.36.199.8.2. The ground state electronic configuration of neutral terbium is [Xe].4f9.6s2 and the term symbol of terbium is 6H15/2.
Terbium is reasonably stable in air. It is a silvery-grey metal, and is malleable, ductile, and soft enough to be cut with a knife. It is a rare earth metal found in cerite, gadolinite and monazite. The element itself was isolated only recently.
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Terbium: physical properties
Terbium: heat properties
- Melting point: 1629 [1356 °C (2473 °F)] K
- Boiling point: 3503 [3230 °C (5846 °F)] K
- Enthalpy of fusion: 20.5 kJ mol-1
Terbium: atom sizes
- Atomic radius (empirical): 175 pm
- Molecular single bond covalent radius: 168 (coordination number 3) ppm
- van der Waals radius: 287 ppm
- Pauling electronegativity: (no data) (Pauling units)
- Allred Rochow electronegativity: 1.10 (Pauling units)
- Mulliken-Jaffe electronegativity: (no data)
Terbium: orbital properties
- First ionisation energy: 565.77 kJ mol‑1
- Second ionisation energy: 1110.8 kJ mol‑1
- Third ionisation energy: 2110 kJ mol‑1
Terbium: crystal structure
Terbium: biological data
- Human abundance by weight: (no data) ppb by weight
Terbium has no biological role.
Reactions of terbium as the element with air, water, halogens, acids, and bases where known.
Terbium: binary compounds
Binary compounds with halogens (known as halides), oxygen (known as oxides), hydrogen (known as hydrides), and other compounds of terbium where known.
Terbium: compound properties
Bond strengths; lattice energies of terbium halides, hydrides, oxides (where known); and reduction potentials where known.
Terbium: historyTerbium was discovered by Carl Mosander in 1843 at Sweden. Origin of name: named after "Ytterby", a town in Sweden.
Isolation: terbium metal is available commercially so it is not normally necessary to make it in the laboratory, which is just as well as it is difficult to isolate as the pure metal. This is largely because of the way it is found in nature. The lanthanoids are found in nature in a number of minerals. The most important are xenotime, monazite, and bastnaesite. The first two are orthophosphate minerals LnPO4 (Ln deonotes a mixture of all the lanthanoids except promethium which is vanishingly rare) and the third is a fluoride carbonate LnCO3F. Lanthanoids with even atomic numbers are more common. The most comon lanthanoids in these minerals are, in order, cerium, lanthanum, neodymium, and praseodymium. Monazite also contains thorium and ytrrium which makes handling difficult since thorium and its decomposition products are radioactive.
For many purposes it is not particularly necessary to separate the metals, but if separation into individual metals is required, the process is complex. Initially, the metals are extracted as salts from the ores by extraction with sulphuric acid (H2SO4), hydrochloric acid (HCl), and sodium hydroxide (NaOH). Modern purification techniques for these lanthanoid salt mixtures are ingenious and involve selective complexation techniques, solvent extractions, and ion exchange chromatography.
Pure terbium is available through the reduction of TbF3 with calcium metal.
2TbF3 + 3Ca → 2Tb + 3CaF2
This would work for the other calcium halides as well but the product CaF2 is easier to handle under the reaction conditions (heat to 50°C above the melting point of the element in an argon atmosphere). Excess calcium is removed from the reaction mixture under vacuum.