โ–ธโ–ธ
  • ๐Ÿ‡ฌ๐Ÿ‡ง Copper
  • ๐Ÿ‡บ๐Ÿ‡ฆ ะœั–ะดัŒ
  • ๐Ÿ‡จ๐Ÿ‡ณ ้Š…
  • ๐Ÿ‡ณ๐Ÿ‡ฑ Koper
  • ๐Ÿ‡ซ๐Ÿ‡ท Cuivre
  • ๐Ÿ‡ฉ๐Ÿ‡ช Kupfer
  • ๐Ÿ‡ฎ๐Ÿ‡ฑ ื ื—ื•ืฉืช
  • ๐Ÿ‡ฎ๐Ÿ‡น Rame
  • ๐Ÿ‡ฏ๐Ÿ‡ต ้Š…
  • ๐Ÿ‡ต๐Ÿ‡น Cobre
  • ๐Ÿ‡ช๐Ÿ‡ธ Cobre
  • ๐Ÿ‡ธ๐Ÿ‡ช Koppar
  • ๐Ÿ‡ท๐Ÿ‡บ ะœะตะดัŒ

Copper - 29Cu: isotope data

Both isotopes of Copper, Cu-63 and Cu-65, are used to study copper metabolism and gastrointestinal diseases. Cu-63 is used for production of medical radioisotope Zn-62 and can also be used for the production of Cu-64 which is used in cancer diagnosis and treatment. Cu-65 has also been proposed as a precursor for the (cyclotron) production of Cu-64.

Naturally occurring isotopes

This table shows information about naturally occuring isotopes, their atomic masses, their natural abundances, their nuclear spins, and their magnetic moments. Further data for radioisotopes (radioactive isotopes) of copper are listed (including any which occur naturally) below.
Isotope Mass / Da Natural abundance (atom %) Nuclear spin (I) Magnetic moment (μ/μN)
63Cu 62.9295989 (17) 69.17 (3) 3/2 2.2233
65Cu 64.9277929 (20) 30.83 (3) 3/2 2.3817
Isotope abundances of copper
Isotope abundances of copper. In the above, the most intense ion is set to 100% since this corresponds best to the output from a mass spectrometer. This is not to be confused with the relative percentage isotope abundances which totals 100% for all the naturally occurring isotopes.

Radiosotope data

Further data for naturally occuring isotopes of copper are listed above. This table gives information about some radiosotopes of copper, their masses, their half-lives, their modes of decay, their nuclear spins, and their nuclear magnetic moments.
Isotope Mass / Da Half-life Mode of decay Nuclear spin Nuclear magnetic moment
59Cu 58.939504 1.36 m EC to 59Ni 3/2
60Cu 59.937368 23.7 m EC to 60Ni 2 1.219
61Cu 60.933462 3.35 h EC to 61Ni 3/2 2.14
62Cu 61.932587 9.74 m EC to 62Ni 1 -0.380
64Cu 63.929768 12.701 h EC to 64Ni; β- to 64Zn 1 -0.217
66Cu 65.928873 5.09 m β- to 66Zn 1 -0.282
67Cu 66.92775 2.580 d β- to 67Zn 3/2
68Cu 67.92964 31 s β- to 68Zn 1
69Cu 68.92943 2.8 m β- to 69Zn 3/2

References

  1. Naturally occurring isotope abundances: Commission on Atomic Weights and Isotopic Abundances report for the International Union of Pure and Applied Chemistry in Isotopic Compositions of the Elements 1989, Pure and Applied Chemistry, 1998, 70, 217. [Copyright 1998 IUPAC]
  2. For further information about radioisotopes see Jonghwa Chang's (Korea Atomic Energy Research Institute) Table of the Nuclides
  3. Masses, nuclear spins, and magnetic moments: I. Mills, T. Cvitas, K. Homann, N. Kallay, and K. Kuchitsu in Quantities, Units and Symbols in Physical Chemistry, Blackwell Scientific Publications, Oxford, UK, 1988. [Copyright 1988 IUPAC]

NMR Properties of copper

Common reference compound: [Cu(NCMe)4]ClO4 in MeCN.

Table of NMR-active nucleus propeties of copper
  Isotope 1 Isotope 2 Isotope 3
Isotope 63Cu 65Cu
Natural abundance /% 69.17 30.83
Spin (I) 3/2 3/2
Frequency relative to 1H = 100 (MHz) 26.515441 28.403658
Receptivity, DP, relative to 1H = 1.00 0.0650 0.0354
Receptivity, DC, relative to 13C = 1.00 371 202
Magnetogyric ratio, γ (107 rad T‑1 s-1) 7.1117890 7.60435
Magnetic moment, μ (μN) 2.8754908 3.07465
Nuclear quadrupole moment, Q/millibarn -220(15) -204(14)
Line width factor, 1056 l (m4) 0.059 0.051

References

  1. R.K. Harris in Encyclopedia of Nuclear Magnetic Resonance, D.M. Granty and R.K. Harris, (eds.), vol. 5, John Wiley & Sons, Chichester, UK, 1996. I am grateful to Professor Robin Harris (University of Durham, UK) who provided much of the NMR data, which are copyright 1996 IUPAC, adapted from his contribution contained within this reference.
  2. J. Mason in Multinuclear NMR, Plenum Press, New York, USA, 1987. Where given, data for certain radioactive nuclei are from this reference.
  3. P. Pyykkö, Mol. Phys., 2008, 106, 1965-1974.
  4. P. Pyykkö, Mol. Phys., 2001, 99, 1617-1629.
  5. P. Pyykkö, Z. Naturforsch., 1992, 47a, 189. I am grateful to Professor Pekka Pyykkö (University of Helsinki, Finland) who provided the nuclear quadrupole moment data in this and the following two references.
  6. D.R. Lide, (ed.), CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Florida, USA, 79th edition, 1998.
  7. P. Pyykkö, personal communication, 1998, 204, 2008, 2010.